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Aluminium hydroxide: Encyclopedia BETA


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Aluminium hydroxide


>| Melting point
Aluminium hydroxide

Aluminium_hydroxide.JPG

General
Systematic nameAluminium(III) hydroxide
Other namesAluminium hydroxide,
Hydrated alumina
Molecular formulaAl(OH)3
Molar mass78.00344 g/mol
AppearanceWhite amorphous powder.
CAS number[]
Properties
Density and phase2.4 g/cm3, solid.
Solubility in waterInsoluble.
?°C
Boiling point?°C
Acidity (pKa)N/A
Hazards
MSDSExternal MSDS
EU classificationIrritant (I)
NFPA 704N/A
R-phrases, ,
S-phrases,
Flash pointNon-flammable.
RTECS numberN/A
Supplementary data page
Structure & properties n, εr, etc.
Thermodynamic data Phase behaviour
Solid, liquid, gas
Spectral dataUV, IR, NMR, MS
Related compounds
Other sNone.
Related compoundsSodium oxide,
aluminium oxide hydroxide.
Except where noted otherwise, data are given for
materials in their standard state (at 25°C, 100 kPa)
Infobox disclaimer and references
Aluminium hydroxide, Al(OH)3, is the most stable form of aluminium in normal conditions. As found in nature it is known as the mineral gibbsite. Closely related are aluminium oxide hydroxide, AlO(OH), and aluminium oxide, Al2O3, differing only by loss of water. These compounds together are the major components of the aluminium ore, bauxite.

The character of 'aluminium hydroxide' has been controversial. It is safe to say that a simple scheme of Al3+ ions and OH- ions is oversimplified. More and less hydrated forms are very common. Some people write Al2O3.xH2O instead.

Aluminium hydroxide is amphoteric. In strongly acid conditions, Al(OH)2+ is formed; in strongly basic conditions, Al(OH)4- is formed. These are the main ions in dilute solutions; in concentrated solutions, polymeric ions are formed which can be quite complex.

Salts of the anion Al(OH)4- (or similar, such as AlO2-) are sometimes called aluminates.

Al(OH)3 has a molar mass of 78.01.

When used, aluminum hydroxide neutralizes the excess acid. For example,Al(OH)3 + 3HCl yields AlCl3 + 3H2O.

Pharmacology

Pharmacologically this compound, also known as Alu-Cap or Aludrox, is used as an antacid. It binds with the excess acid in the stomach, thus reducing its acidity. This decrease of acidity of the contents of the stomach may in turn help to relieve the symptoms of ulcers, heartburn or dyspepsia. It can also cause constipation and is therefore often used with magnesium carbonate.This compound is also used to control phosphate levels in the blood for people suffering from kidney failure. However, there are unverified claims that excessive consumption of aluminium is a cause of Alzheimer's disease.

References

Galbraith, A; Bullock, S; Manias, E. Hunt, B. & Richards, A. (1999). Fundamentals of pharmacology: a text for nurses and health professionals. Harlow: Pearson Education Ltd. p482.

External links

* International Chemical Safety Card 0373
* External MSDS Sheet.



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